From the total synthesis of longifolene. Interesting contradiction of violating Bredt's rule, but the cation being stabilized by the double bond. Further discussion of stabilization can be found on LibreTexts. The screenshot RE: Bredt's Rule is from
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A very nice example of the Corey-Chaykovsky reaction from the total synthesis of fumagillol. Found originally on one of my favorite resource pages, Organic Chemistry Data, that archives total syntheses by the name reactions they contain! Categories All |
Mechanism MondaysA new organic chemistry mechanism each Monday, with the answer posted a few hours later. Archives
January 2024
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